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Writer's pictureZERI China | Zero Emissions Research and Initiatives

Natural Solutions for Fire Control: The Impact of Citrus-Based Innovations


The Blue Economy - CASE 16: Fire and Flame Control with Citrus


This article introduces innovations in consumer safety that shape the Blue Economy, which is known as ZERIʼs philosophy in action. It is part of a broad effort by the author and designer of the Blue Economy to stimulate open-source entrepreneurship, competitiveness, and employment. Researched, Written, and Updated by Professor Gunter Pauli.


 

The Blue Economy Inspired Series


Natural Solutions for Fire Control:

The Impact of Citrus-Based Innovations


Written by; Shelley Tsang, 2024.



In an era marked by increasing awareness of environmental sustainability and consumer safety, innovative solutions are emerging that not only enhance safety but also promote the principles of the Blue Economy. Among these innovations is the development of flame retardants derived from natural sources, particularly citrus and grape waste. This article delves into the market dynamics, the groundbreaking technology behind "Molecular Heat Eaters," and the vast opportunities these innovations present for a safer and more sustainable future.



The Market Landscape for Fire Retardants


The global market for fire and flame retardants was estimated at $5.1 billion in 2012, with projections indicating growth to $7.1 billion by 2017. The demand for halogen-free fire retardants, which are increasingly preferred due to health concerns, has already reached $2.72 billion and continues to expand. In regions such as Europe and Japan, health-conscious consumers are driving the transition away from hazardous halogenated compounds, which have come under scrutiny for their potential health impacts. Meanwhile, demand in the Asia-Pacific region, particularly in China, is surging, with an anticipated growth rate exceeding 13% annually.


Historically, flame retardants have been integrated into various products ranging from textiles to electronics, often driven by regulatory requirements and insurance standards. However, the chemicals traditionally used for flame resistance, many of which are brominated or halogenated, have been linked to serious health issues, including neurological disorders, cancer, and reproductive toxicity. As awareness of these risks grows, the industry is increasingly compelled to seek safer alternatives.



The Need for Safer Alternatives


The use of flame retardants in consumer products has escalated since the early 20th century when synthetic materials became prevalent. Fire safety regulations mandated the inclusion of these chemicals in items like couches, electronics, and children's toys, ostensibly to reduce fire hazards. Ironically, the very chemicals designed to enhance safety have introduced new health risks, raising critical questions about their long-term impact on human health and the environment.


Research has identified that many flame retardants can bioaccumulate in human tissues, leading to chronic exposure and associated health risks. This has led to growing consumer demand for non-toxic alternatives and stringent government regulations aimed at phasing out harmful substances. In response, innovators in the field of chemistry are exploring novel solutions that are both effective in fire suppression and safe for human health.



The Innovation: Molecular Heat Eaters


Among the most promising innovations in this domain is the creation of "Molecular Heat Eaters" (MHE), developed by Mats Nilsson, a Swedish inventor. This groundbreaking approach leverages food-grade chemicals, drawing inspiration from natural processes. The MHE utilizes an acid-base reaction to create a highly exothermic process that generates a protective barrier against fire.


Nilsson's journey began with an anecdote from his grandfather, a welder who noticed that cider spilt on his clothes seemed to render them resistant to sparks. Building upon this observation, Nilsson designed a reaction between an organic acid and an inorganic base that generates a significant amount of energy, producing a fire-retardant barrier when temperatures rise. The MHE binds oxygen, effectively consuming it and forming water while generating carbon-rich char—a non-combustible material that serves to inhibit fire propagation.



The Science Behind MHE


To understand how MHE works, it is essential to grasp the fundamental chemistry involved. Fire requires three components: oxygen, heat, and a combustible material. The MHE system works by consuming oxygen and producing carbon-based char that covers the surface of materials, thereby creating a barrier that prevents heat transfer and flame spread.


By utilizing raw materials sourced from grape pomace and citrus waste, the MHE addresses two significant challenges: it promotes sustainability by recycling agricultural waste and provides a non-toxic alternative to traditional flame retardants. The particles produced by MHE are tiny and biodegradable, significantly increasing their surface area and enhancing the speed of chemical reactions. This efficiency means that less fire retardant is required compared to conventional products, presenting a compelling economic advantage.



First Cash Flow: Commercial Viability


The primary challenge for the MHE technology lies in optimizing its blending into various products. Different materials, such as PVC, require tailored concentrations of MHE to ensure effective fire resistance. After extensive research and development, Nilsson and his team have created a portfolio of applications across a range of industries, including textiles, construction, and transportation.


Trulstech AB, founded by Nilsson, has entered into licensing agreements with companies in the United States and Australia, allowing for a broader distribution of MHE technology. The Swedish partner, Deflamo AB, has successfully launched the fire retardant under the brand name Apyrum© and has established full-scale manufacturing operations. This innovative approach not only offers a viable product but also signals a shift in the industry towards more sustainable practices.



Expanding Applications and Future Opportunities


The potential applications of MHE are vast and varied. From fire-resistant carpets used in commercial aircraft to protective casings for electronic devices, the versatility of this technology is noteworthy. The use of food-grade materials opens up possibilities for environmental-friendly chemistry in sectors that have traditionally relied on toxic substances.


One of the most intriguing prospects is the potential application of MHE in firefighting. The ability to mist MHE in environments prone to ignition, such as mining operations, could revolutionize safety measures by providing an extra layer of protection against fire hazards. While this concept is still in the exploratory phase, its implications for reducing fire risks in high-stakes environments are profound.


Additionally, MHE has the potential to contribute to the recycling economy by valorizing agricultural waste. Wine-producing regions could benefit economically from transforming grape pomace into valuable fire-retardant materials, creating a circular economy model that supports local agriculture while addressing environmental concerns.



Conclusion: A New Era of Flame Control


The development of fire retardants derived from citrus and grape waste represents a transformative shift in the industry, combining safety, sustainability, and economic viability. As consumers and regulators alike demand safer alternatives to traditional flame retardants, innovations like Molecular Heat Eaters pave the way for a future where fire safety does not come at the cost of human health or environmental integrity.


By embracing these innovations, we can move towards a more sustainable future where waste is not merely discarded but repurposed into valuable products. The journey towards safe, effective, and eco-friendly flame control is just beginning, and it holds the promise of creating a safer world for generations to come. As entrepreneurs and innovators around the globe recognize the potential of MHE and similar technologies, we can expect to see a significant transformation in the fire safety landscape, ultimately benefiting consumers, industries, and the planet alike.





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